Shakugan no Shana: Deep Love

With Tiriel clinging to Sorath's shoulder, she and her older brother defiantly face forward

Sorath / Aizenji (He Who Loves Himself), despite being the older sibling, acts more childish and carefree than his devoted, protective, and mature younger sister, Tiriel / Aizenta (One Indulged in Love of Others), but both are quite serious about consuming the Power of Existence of humans to survive.
From the anime series Shakugan no Shana

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